有機(jī)金屬化學(xué)

內(nèi)容概要

整個(gè)世界又一次走在十字路口，全球各國似乎都處在一個(gè)個(gè)“局”中：美國、歐洲、日本等國深陷債務(wù)“危局”，窮于應(yīng)付；平等、自由等傳統(tǒng)的價(jià)值觀受到了強(qiáng)烈的質(zhì)疑，資本主義世界深陷“困局”，歐美自工業(yè)革命后建立的世界秩序遭遇嚴(yán)重的沖擊；席卷世界的債務(wù)危機(jī)背后則隱藏著巨大的理論困境，經(jīng)濟(jì)學(xué)家身陷“迷局”，西方經(jīng)濟(jì)學(xué)的局限性暴露無遺，凱恩斯及新自由主義的經(jīng)濟(jì)政策面對(duì)危機(jī)早已束手無策。
面對(duì)波詭云譎的國際時(shí)局，《有機(jī)金屬化學(xué)（原第2版 國際版）》作者根據(jù)多年的研究，從兩部類模型出發(fā)，創(chuàng)新地發(fā)展了馬克思主義經(jīng)濟(jì)學(xué)對(duì)債務(wù)危機(jī)進(jìn)行“破局”，為人們觀察、了解世界債務(wù)提供了一個(gè)全新的視角，為“中國模式”注入了新的內(nèi)容，對(duì)世界經(jīng)濟(jì)形勢進(jìn)行前瞻性的思考。作者憑借深厚的學(xué)術(shù)功底及豐富的文史知識(shí)，從文化、歷史、宗教、經(jīng)濟(jì)、政治、軍事、地緣等方面展現(xiàn)了精彩紛呈的世界“大棋局”。

作者簡介

勾紅洋
青年學(xué)者，曾任深圳鴻榮源集團(tuán)首席經(jīng)濟(jì)分析師，國內(nèi)運(yùn)用馬克思主義經(jīng)濟(jì)學(xué)對(duì)中國GDP核算體系進(jìn)行系統(tǒng)修正的第一人。對(duì)世界經(jīng)濟(jì)有全面獨(dú)到的認(rèn)識(shí)，力圖尋找一條馬克思主義經(jīng)濟(jì)學(xué)與現(xiàn)代西方經(jīng)濟(jì)學(xué)的結(jié)合之路，使之能與普通人的生活緊密聯(lián)系。著有《低碳陰謀》《算算中國家底》《第七次財(cái)富潮》等財(cái)經(jīng)暢銷書。

書籍目錄

前言 這個(gè)世界怎么了?第一篇 危局,被債務(wù)綁架的世界第一章 債務(wù)危機(jī)洶洶來襲巔峰墜落,美國的驚人衰敗歐洲,正在懸崖邊緣日本是個(gè)無底洞中國沒有例外第二章 無法破解的難題?是誰設(shè)置如此巨大的陷阱,李嘉圖還是凱恩斯?美元的詛咒從次貸危機(jī)到債務(wù)危機(jī),一場沒有終點(diǎn)的救援世界經(jīng)濟(jì)將走向何方?下一個(gè)凱恩斯在哪里?第二篇 困局,債務(wù)危機(jī)沖擊下的無序世界第三章 資本主義病入膏肓歷史真的終結(jié)了嗎?誰在制定先進(jìn)與落后的標(biāo)準(zhǔn)民主,一場蓄意的騙局貧富懸殊,放任自由的幻滅高福利折騰完了,資本主義只剩下一具空殼第四章 坍塌的世界秩序打破平衡的臨界點(diǎn)從G8到G20,權(quán)杖的移交阿拉伯成為關(guān)鍵先生“文明沖突”的沖突第三篇 謎局,揭開債務(wù)危機(jī)背后的重重魅影第五章 不能回避馬克思破除“李嘉圖惡習(xí)”老革命與新問題發(fā)展馬克思主義經(jīng)濟(jì)學(xué)的突破口回到現(xiàn)實(shí)世界第六章 并不深?yuàn)W的答案產(chǎn)業(yè)空心化,歐美不可承受之重望眼欲穿的科技革命掠奪難以為繼貧富分化,從大蕭條到債務(wù)危機(jī)的內(nèi)在邏輯第四篇 破局,中國模式的成功與定型第七章 中國模式,破解危機(jī)的必然參照?德國為什么成為例外?中國如何成為債務(wù)危機(jī)中的中流砥柱中國經(jīng)濟(jì)成功的原因探析第八章 在歷史中尋找未來古希臘的明燈約束資本的力量厘定政府的權(quán)力邊界國家會(huì)計(jì)是重要的手段第五篇 大棋局,未來世界的格局和方向第九章 未來十年的走勢復(fù)雜性世界的到來美國最終的選擇——退回美洲俄羅斯大國夢破歐洲有沒有機(jī)會(huì)把握未來?第十章 中國,如何實(shí)現(xiàn)“中央突圍”中國的現(xiàn)實(shí)困境——逆全球化悄然臨近高鐵,中國戰(zhàn)勝危機(jī)最現(xiàn)實(shí)的選擇馬克思主義經(jīng)濟(jì)學(xué)的旗幟要舉多高?

章節(jié)摘錄

版權(quán)頁：   插圖：   An Overview of Organometallic Chemistry Organometallic chemistry, the chemistry of compounds containing metalcarbon bonds, is one of the most interesting and certainly most rapidly growing areas of chemical research. It encompasses a wide variety of chemical compounds and their reactions: compounds containing both sigma （σ） and pi（π） bonds between metal atoms and carbon; many cluster compounds, containing two or more metal-metal bonds; molecules containing carbon fragments that are unusual or unknown in orgaruc chemistry; and reactions that in some cases bear similarities to known organic reactions-and in other cases are dramaticallydifferent. Aside from their intrinsically interesting nature, many organometallic compounds form useful catalysts and, consequently, are of significant industrial interest. Over the past several years, organometallic reagents have played the role of promoting key steps in the total synthesis of numerous molecules, many of which are biologically active. 1-1 STRIKING DIFFERENCE Several examples illustrate how organometallic molecules are strikingly different from those encountered in classical inorganic and organic chemistry. Ligands of cyclic delocalized π systems （e.g., benzene or cyclopentadienyl） can teamup with metal atoms to form “sandwich" compounds with a metal sandwiched between them. Sometimes atoms of other elements, such as phosphorus or sulfur,can be included as well. Examples of these double- and multiple-decker sandwich compounds are shown in Figure 1-1. The structure and bonding of sandwich compounds will be discussed in Chapter 4. A characteristic of metal atoms bonded to organic ligands, especially CO （the most common of allligands in organometallic chemistry）,is that they often exhibit the capacity to form covalent bonds to other metal atoms to form dinuclear complexes and polynuclear cluster compounds （some known cluster compounds contain no organic ligands）. These clusters may contain only three metal atoms or as many as several dozen; there is no limit to their size or variety. Dinuclear complexes may contain single, double, triple, or even quadruple bonds between the metal atoms and may in some cases have ligands that bridge two or more of the metals. Examples of metal cluster compounds containing organic ligands are shown as structures a, b, and c in Figure 1-2; cluster complexes will be encountered again in Chapter 11.Carbon itself may play quite a different role than commonly encountered in organic chemistry. Certain metal clusters encapsulate carbon atoms; the resulting molecules, called carbide clusters, in some cases contain carbon bonded to five,six, or more surrounding metals. Figures 1-2d and e illustrate two examples of carbide clusters.

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　　“……該書是有機(jī)金屬化學(xué)的經(jīng)典教科書，內(nèi)容深入淺出……書中大量的練習(xí)題直接取自實(shí)際的研究工作……特別適合于第一次系統(tǒng)學(xué)習(xí)該課程的研究生和高年級(jí)本科生……　　——王劍波，北京大學(xué)化學(xué)與分子工程學(xué)院

編輯推薦

《國外化學(xué)經(jīng)典教材系列7(影印版):有機(jī)金屬化學(xué)(原著第2版)(國際版)》是有機(jī)金屬化學(xué)經(jīng)典教科書，內(nèi)容深入淺出，書中大量的練習(xí)題直接取自實(shí)際的研究工作，特別適合于第一次系統(tǒng)學(xué)習(xí)該課程的研究生和高年級(jí)本科生。

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