光電子光譜學(xué)

前言

　　Since the completion of the manuscript for the first edition of PhotoelectronSpectroscopy， the field has undergone a steady growth.　　Firstly， the theory has been refined and condensed into a manageableform. Secondly two important experimental developments have occurred. Theresolution that can be obtained is now of the order of 3 meV， which corre-sponds approximately to an energy of 30 kBK. This means that photoelectronspectroscopy can now obtain data with an accuracy similar to that achievedin standard thermodynamic experiments （such as specific heat experiments），thus facilitating a direct comparison of data from the two different types ofexperiment. The second important experimental advance is that one can nowreadily measure electron energy distributions over a solid angle of almost This yields valuable information whenever these electron energy distributionshave anisotropies. It was decided， in view of these developments， to rework and expandthe volume so as to do justice to the full potential of todays photoelectronspectroscopy. I have benefitted very much from the help of my group namelyR. de Masi， D. Ehm， B. Eltner， F. Miiller， G. Nicolay， F. Reinert， D. Reinickeand in particular S. Schmidt. Without the dedicated effort of these collabo-rators the present edition could not have been produced. I am grateful to S.Neumann who typed the complete text with great skill. Thanks are due tothe Springer Verlag for their expert help and patience.

內(nèi)容概要

　　Since the completion of the manuscript for the first edition of PhotoelectronSpectroscopy， the field has undergone a steady growth.Firstly， the theory has been refined and condensed into a manageableform. Secondly two important experimental developments have occurred. Theresolution that can be obtained is now of the order of 3 meV， which corre-sponds approximately to an energy of 30 kBK. This means that photoelectronspectroscopy can now obtain data with an accuracy similar to that achievedin standard thermodynamic experiments （such as specific heat experiments），thus facilitating a direct comparison of data from the two different types ofexperiment. The second important experimental advance is that one can nowreadily measure electron energy distributions over a solid angle of almost This yields valuable information whenever these electron energy distributionshave anisotropies.

書籍目錄

1. Introduction and Basic Principles　1.1  Historical Development　1.2  The Electron Mean Free Path　1.3  Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy　1.4  Experimental Aspects　1.5  Very High Resolution　1.6  The Theory of Photoemission　　1.6.1  Core-Level Photoemission　　1.6.2  Valence-State Photoemission　　1.6.3  Three-Step and One-Step Considerations　1.7  Deviations from the Simple Theory of Photoemission　References2. Core Levels and Final States　2.1  Core-Level Binding Energies in Atoms and Molecules　　2.1.1  The Equivalent-Core Approximation　　2.1.2  Chemical Shifts　2.2  Core-Level Binding Energies in Solids　　2.2.1  The Born-Haber Cycle in Insulators　　2.2.2  Theory of Binding Energies　　2.2.3  Determination of Binding Energies and Chemical Shifts from Thermodynamic Data  　2.3  Core Polarization　2.4  Final-State Multiplets in Rare-Earth Valence Bands　2.5  Vibrational Side Bands　2.6  Core Levels of Adsorbed Molecules　2.7  Quantitative Chemical Analysis from Core-Level Intensities　References3. Charge-Excitation Final States: Satellites  3.1  Copper Dihalides; 3d Transition Metal Compounds　　3.1.1  Characterization of a Satellite　　3.1.2  Analysis of Charge-Transfer Satellites　　3.1.3  Non-local Screening　 3.2  The 6-eV Satellite in Nickel　　3.2.1  Resonance Photoemission　　3.2.2  Satellites in Other Metals　3.3  The Gunnarsson-Sch6nhammer Theory　3.4  Photoemission Signals and Narrow Bands in Metals 　References4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems　4.1  Theory　　4.1.1  General　　4.1.2  Core-Line Shape　　4.1.3  Intrinsic Plasmons　　4.1.4  Fxtrinsic FAectron Scattering: Plasmons and Background　　411.5  The Total Photoelectron Spectrum　4.2  Experimental Results　　4.2.1  The Core Line Without Plasmons　　4.2.2  Core-Level Spectra Including Plasmoas　　4.2.3  Valence-Band Spectra of the Simple Metals　　4.2.4  Simple Metals: A General Comment　4.3  The Background Correction　References5. Valence Orbitals in Simple Molecules and Insulating Solids　5.1  UPS Spectra of Monatomic Gases　5.2  Photoelectron Spectra of Diatomic Molecules　5.3  Binding Energy of the H2 Molecule　5.4  Hydrides Isoelectronic with Noble Gases　　Neon (Ne)　　Hydrogen Fluoride (HF)　　Water (H2O)　　Ammonia (NH3)　　Methane (CH4)　5.5  Spectra of the Alkali HMides　5.6  Transition Metal Dihalides　5.7  Hydrocarbons　　5.7.1  Guidelines for the Interpretation of Spectra from Free Molecules　　5.7.2  Linear Polymers  5.8  Insulating Solids with Valence d Electrons　　5.8.1  The NiO Problem　　5.8.2  Mort Insulation  ……6. Photoemission of Valence Electrons from Metallic Solids in the One-Electron Approximation7. Band Structure and Angular-Resolved Photoelectron Spectra8. Surface States, Surface Effects9. Inverse Photoelectron Spectroscopy10. Spin-Polarized Photoelectron Spectroscopy11. Photoelectron DiffractionAppendixIndex

章節(jié)摘錄

　　Secondly two important experimental developments have occurred. Theresolution that can be obtained is now of the order of 3 meV, which corre-sponds approximately to an energy of 30 kBK. This means that photoelectronspectroscopy can now obtain data with an accuracy similar to that achievedin standard thermodynamic experiments （such as specific heat experiments）,thus facilitating a direct comparison of data from the two different types ofexperiment. The second important experimental advance is that one can nowreadily measure electron energy distributions over a solid angle of almost This yields valuable information whenever these electron energy distributionshave anisotropies. It was decided, in view of these developments, to rework and expandthe volume so as to do justice to the full potential of todays photoelectronspectroscopy. I have benefitted very much from the help of my group namelyR. de Masi, D. Ehm, B. Eltner, F. Miiller, G. Nicolay, F. Reinert, D. Reinickeand in particular S. Schmidt. Without the dedicated effort of these collabo-rators the present edition could not have been produced.

編輯推薦

　　《光電子光譜學(xué)：原理和應(yīng)用(第3版)》由胡夫尼編著。It was decided， in view of these developments， to rework and expandthe volume so as to do justice to the full potential of todays photoelectronspectroscopy. I have benefitted very much from the help of my group namelyR. De Masi， D. Ehm， B. Eltner， F. Miiller， G. Nicolay， F. Reinert， D. Reinickeand in particular S. Schmidt. Without the dedicated effort of these collabo-rators the present edition could not have been produced. I am grateful to S.Neumann who typed the complete text with great skill. Thanks are due to the Springer Verlag for their expert help and patience.

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