實驗室化學品的純化

內容概要

　　《實驗室化學品的純化(第5版)》在介紹提純相關技術(重結晶、干燥、色譜、蒸餾、萃取、衍生物的制備等)基礎上，詳細介紹了化學品的純化方法，例如重結晶的溶劑選擇，常壓和減壓蒸餾的沸點，純化以前的處理手續(xù)等。從粗略純化到高度純化都有詳細說明，并附參考文獻。給出了幾乎所有商品化有機化學品、無機化學品以及生化試劑的基本理化性質和純化過程，包括名稱、CAS登錄號、分子量、熔點、沸點、相對密度、溶解性、離子化常數(shù)等。

作者簡介

作者：(澳大利亞)柴(Chai C．L．L．) (澳大利亞)阿瑪瑞高(ArmaregoW．L．F．)

書籍目錄

Preface to the Fifth EditionPreface to the First EditionPreface to the Second EditionPreface to the Third EditionPreface to the Fourth EditionCHAPTER 1COMMON PHYSICAL TECHNIQUES USED IN PURIFICATIONINTRODUCTIONTHE QUESTION OF PURITYSOURCES OF IMPURITIESPRACTICES TO AVOID IMPURITIESCleaning practicesSilylation of glassware and plasticwareSAFETY PRECAUTIONS ASSOCIATED WITH THE PURIFICATION OF LABORATORY CHEMICALSSOME HAZARDS OF CHEMICAL MANIPULATION IN PURIFICATION AND RECOVERY OF RESIDUESPerchlorates and perchloric acidPeroxidesHeavy-metal-containing-explosivesStrong acidsReactive halides and anhydridesSolventsSaltsSAFETY DISCLAIMERMETHODS OF PURIFICATION OF REAGENTS AND SOLVENTSSOLVENT EXTRACTION AND DISTRIBUTIONIonisation constants and pKpK and TemperaturepK and solventDISTILLATIONTechniquesDistillation of liquid mixturesTypes of distillationThe distilling flaskTypes of columns and packingsCondensersVacuum distillationSpinning-band distillationSteam distillationazeotropic distillation  ii...iiiiKiigelrohr distillationlsopiestic or isothermal distillationRECRYSTALLISATIONTechniquesFiltrationChoice of solventsPetroleum ethersMixed SolventsRecrystaUisation from the meltZone refiningSUBLIMATIONCHROMATOGRAPHYVapour phase chromatography (GC or gas-liquid chromatography)Liquid chromatographyAdsorption chromatographyThin layer chromatography (TLC)Paper chromatographyColumn ChromatographyGraded Adsorbents and SolventsPreparation and Standardisation of AluminaPreparation of other adsorbentsSilicaDiatomaceous earthCharcoalCelluloseFlash ChromatographyPaired-ion ChromatographyIon-exchange ChromatographyIon-exchange ResinsIon-exchange Celluloses and SephadexSephadexSepharoseCeUex CMCellex DCrystalline HydroxyiapatiteGel FiltrationHigh Performance Liquid Chromatography (HPLC)Other Types of Liquid ChromatographyDRYINGRemoval of SolventsRemoval of WaterIntensity and Capacity of Common DesiccantsSuitability of Individual DesiccantsMolecular sievesMISCELLANEOUS TECHNIQUESFreeze-pump-thaw and purgingVacuum-lines, Schlenk and glovebox techniquesABBREVIATIONSTABLESTABLE  1.  SOME COMMON IMMISCIBLE OR SLIGHTLY MISCIBLE PAIRS OF SOLVENTSTABLE  2.  AQUEOUS BUFFERSTABLE  3A.  PREDICTED EFFECT OF PRESSURE ON BOILING POINTTABLE  3B.  PREDICTED EFFECT OF PRESSURE ON BOILING POINTFIGURE  1:  NOMOGRAMTABLE  4.  HEATING BATHSTABLE  5.  WHATMAN FILTER PAPERSTABLE  6.  MICRO FILTERSTABLE  7.  COMMON SOLVENTS USED IN RECRYSTALLISATIONTABLE  8.  PAIRS OF MISCIBLE SOLVENTSTABLE  9.  MATERIALS FOR COOLING BATHSTABLE  10.  LIQUIDS FOR STATIONARY PHASES IN GAS CHROMATOGRAPHYTABLE  11.  METHODS OF VISUALISATION OF TLC SPOTSTABLE  12.  GRADED ADSORBENTS AND SOLVENTSTABLE  13.  REPRESENTATIVE ION-EXCHANGE RESINSTABLE  14.  MODIFIED FIBROUS CELLULOSES FOR ION-EXCHANGETABLE  15.  BEAD FORM ION-EXCHANGE PACKAGINGSTABLE  16.  LIQUIDS FOR DRYING PISTOLSTABLE  17.  VAPOUR PRESSURES (mm Hg) OF SATURATED AQUEOUS SOLUTIONS IN EQUILIBRIUM WITH SOLID SALTSTABLE  18.  DRYING AGENTS FOR CLASSES OF COMPOUNDSTABLE  19.  STATIC DRYING FOR SELECTED LIQUIDS (25~C)TABLE 20.  BOILING POINTS OF SOME USEFUL GASES AT 760 mmTABLE 21.  SOLUBILITIES OF HC1 AND NH3 AT 760mm (g/100g OF SOLUTION)TABLE 22.  PREFIXES FOR QUANTITIESBIBLIOGRAPHYCHAPTER 2CHEMICAL METHODS USED IN PURIFICATIONGENERAL REMARKSREMOVAL OF TRACES OF METALS FROM REAGENTSMETAL IMPURITIESDISTILLATIONUSE OF ION EXCHANGE RESINSPRECIPITATIONRemoval of lead contaminantsRemoval of iron contaminantsRemoval of other metal contaminantsEXTRACTIONCOMPLEXATIONUSE OF METAL HYDRIDESLITHIUM ALUMINIUM HYDRIDECALCIUM HYDRIDESODIUM BOROHYDRIDEPOTASSIUM BOROHYDRIDEPURIFICATION via DERIVATIVESALCOHOLSALDEHYDESAMINESPicratesSaltsDouble saltsN-Acetyl derivativesN-Tosyl derivativesAROMATIC HYDROCARBONSAdductsSulfonationCARBOXYLIC ACIDS4-Bromophenacyl estersAlkyl estersSaltsHYDROPEROXIDESKETONESBisulfite adductSemicarbazonesPHENOLSBenzoatesAcetatesPHOSPHATE AND PHOSPHONATE ESTERSMISCELLANEOUSGENERAL METHODS FOR THE PURIFICATION OF CLASSES OF COMPOUNDSPROCEDURESCRITERIA OF PURITYGENERAL PROCEDURES FOR THE PURIFICATION OF SOME CLASSES OF ORGANICCOMPOUNDSACETALSACIDSCarboxylic acidsSulfonic acidsSulfinic acidsACID CHLORIDESALCOHOLSMonohydric alcoholsPolyhydric alcoholsALDEHYDESAMIDESAMINESAMINO ACIDSANHYDRIDESCAROTENOIDSESTERSETHERSHALIDESHYDROCARBONSIMIDESIMINO COMPOUNDSKETONESMACROMOLECULESNITRILESNITRO COMPOUNDSNUCLEIC ACIDSPHENOLSPOLYPEPTIDES AND PROTEINSQUINONESSALTS (ORGANIC)With metal ionsWith organic cationsWith sodium alkane sulfonatesSULFUR COMPOUNDSDisulfidesSulfonesSulfoxidesThioethersThiolsThiolsulfonates (disulfoxides)BIBLIOGRAPHYCHAPTER 3THE FUTURE OF PURIFICATIONINTRODUCTIONSOLID PHASE SYNTHESISSOLID PHASE PEPTIDE SYNTHESIS (SPPS)SOLID PHASE DEOXYRIBONUCLEOTIDE SYNTHESISSOLID PHASE OLIGOSACCHARIDE SYNTHESISSOLID PHASE ORGANIC SYNTHESIS (SPOS)POLYMER SUPPORTED REACTANTSSCAVENGER RESINSRESIN SUPPORTCHOICE OF RESIN FOR SPOSCOMBINATORIAL CHEMISTRYMONITORING SOLID PHASE REACTIONSInfra red analysis of resinQualitative and quantitative analysesDETECTION OF REACTIVE GROUPS ON RESINSDetection of hydroxy groups on resinDetection of aldehyde groups on resinDetection of carboxy groups on resinDetection of amino groups on resinDetection of thiol groups on resinFmoc assayIONIC LIQUIDSFLUOROUS CHEMISTRYBIBLIOGRAPHYCHAPTER 4PURIFICATION OF ORGANIC CHEMICALSCHAPTER 5PURIFICATION OF INORGANIC AND METALORGANIC CHEMICALS(Including Organic compounds of B, Bi, P, Se, Si, and ammonium and metal salts of organic acids)CHAPTER 6PURIFICATION OF BIOCHEMICALS AND RELATED PRODUCTSGENERAL SUBJECT INDEXCAS REGISTRY NUMBERS INDEX

編輯推薦

《實驗室化學品的純化(第5版)》是廣大實驗室工作人員必備的工具書。

圖書封面

評論、評分、閱讀與下載

---

    實驗室化學品的純化 PDF格式下載

---