高分子物理導(dǎo)論

內(nèi)容概要

No Previous knowledge of polymers is assumed in this book which provides a general introduction to the physics of solid polymers.    The book covers a wide range of topics within the field of polymer physics,beginning with a brief histor of hte developmert of synthetic polymers and an overview of the methods of polymerisation and processing .In the following chapter,David Bower describes important experimenttal techniques used in the study of polymers.The main part of the book,however,is deoted to the structure and properties of solid polymers,including blends,copolymers and liquid-crystal polymers,     With an approach appropricate for advanced undergraduate and graduate students of physics,materials science and chemistry,the book includes many worked examples and problems with solutions It will provide a firm firm foundation for the study of the physics of solid polymers.作者簡介：    DAVID BOWER received his D.Phil.from the University of Oxford in 1964.In 1990 he became a reader in the Department of Physics at the Universiyt of Leeds,retiring from this position in 1995.He was a founder member of the management committee of the IRC in Polymer Science and Technology(Universities of Leeds,Durham and Bradford),and co-authored The Vibrational Spectrosopy of Polymers with W.F.Maddams(CUP,1989).His contribution to the primary literature has included work on polymers,solid-state physics and magnetism.

書籍目錄

PrefaceAcknowledgements1 Introduction 1.1 Polymers and the scope of the book 1.2 A brief history of the development of synthetic polymers 1.3 The chemical nartue of polymers  1.4 Properties and applications 1.5 Polymer processing 1.6 Further reading2 Some physical tecniques for studying polymers 2.1 Introduction 2.2 Differential scanning calorimetry (DSC)and differential thermal      analysis(DTA) 2.3 Density measurement 2.4 Light scattering 2.5 X-ray scattering 2.6 Infrared and Raman spectroscopy 2.7 Nuclear magnetic resonanec spetroscopy(NMR) 2.8 Optical and electron microscopy 2.9 Further reading3 Molecular sizes and shapes and ordered structures 3.1 Introduction 3.2 Distributions of molar mass and their determination 3.3 The shapes of polymer molecules 3.4 Evidence for ordered structures in solid polymers 3.5 Further reading 3.6 Problems4 Regular chaing and crystallinity 4.1 Regular and irregular chains 4.2 The determination of crystal structures by X-ray diffraction 4.3 Information about crystal structures from other methods  4.4 Crystal structures of some common polymers 4.5 Further reading 4.6 Problems5 Morphology and motion 5.1 Introduction 5.2 The degree of crystallinity 5.3 Crystallites 5.4 Non-crystalline regions and polymer macro-comformations 5.5 Spherulites and other polycrstalline structures 5.6 Crystallisation and melting  5.7 Molecular motion 5.8 Further reading 5.9 Problems6 Mechanical properties I-time-independent elasticity 6.1 Introduction to the mechanical properties of polymers 6.2 Elastic properties of isotropic polymers at small strains 6.3 The phenomenology of rubber elasticity 6.4 The statistical theory of rubber elasticity 6.5 Modifications of the simple molecular and phenomenological theories 6.6 Further reading 6.7 Problems7 Mechanical properties II-linear viscoelasticity 7.1 Introduction and definitions 7.2 Mechanical models 7.3 Experimental methods for studyingviscoelastic behaviour  7.4 Time-temperature equivalence and superposition 7.5 The glass transition in amorphous polymers 7.6 Relaxations for amorphous and crystalline polymers 7.7 Further reading 7.8 Problems8 Yield and fracture of polymers 8.1 Introduction 8.2 Yield 8.3 Fracture 8.4 Further reading 8.5 Problems9 Electrical and optical properties 9.1 Introduction 9.2 Electrical Polarisation 9.3 Conducting polymers 9.4 Optical properties of polymers 9.5 Further reading 9.6 Further reading10 Oriented polymers I-production and characterisation 10.1 Introductin-hte meaning and importance of orientation 10.2 The productin of orientation in synthetic polymers 10.3 The mathematical description of molecular orientation 10.4 Methods of representingtypes of orientation 10.5 The combination of methods for two-phase systems 10.6 Methods of representing types of orientatin 10.7 Further reading 10.8 Problems11 Oriented polymers II-models and properties 11.1 Introduction 11.2 Models for molecular orientation 11.3 Comparison between theory and experiment 11.4 Comparison between predicted and observed elastic properties 11.5 Takayanagi composite models 11.6 Highly oriented polymers nad ultimate moduli 11.7 Further reading 11.8 Problems12 Polymer blends,copolymers and liquid-crystal polymers 12.1 Introduction 12.2 Polymer blends 12.3 Copolymers 12.4 Liquid-crystal polymers 12.5 Further reading 12.6 ProblemsAppendix:cartesian tensorsSolutions to problemsIndex

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